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Victor Meyer: A celebrated chemist
VICTOR MEYER was born (September 8, 1848, Berlin) in a wealthy
Jewish family. As a boy he showed keen interest in the theatre
and wanted to become an actor: These gifts were to be employed
later as a scholarly and effective teacher. But his family
persuaded him to attend lectures at Heidelberg.
Meeting the chemist Robert Bunsen, his interests changed to
chemistry. Besides Kopp and Bunsen, his teachers were Kirchoff
and Helmholtz, all eminent scientists. He topped the class in all
his courses and was awarded the Ph.D., `Summa cum laude' at the
young age of 18. Meyer worked as assistant to Bunsen for one
year, performing analysis of the mineral waters of Baden. He
worked for three years (1868- 71) in Baeyer's lab, when he began
publishing in organic chemistry.
In 1871, he became Professor at the Stuttgart polytechnic. His
career was spread among three famous centres of learning -
Federal Institute of Technology, Zurich (1872-85), University of
Goettingen (1885- 88) and University of Heidelberg (1889-97). It
was the efforts of Bunsen that enabled Meyer to obtain release
from Goeltingen and became his successor at Heidelberg, which
proved to be good fortune for chemistry.
Meyer and his students published more than 300 papers, many of
fundamental importance. HIs first significant paper (1870)
described a new method for introducing the carboxyl group into an
aromatic substance by heating potassium salts of aromatic
sulfonic acids with sodium formate. This method has been used
ever since by organic chemists for the synthesis of aromatic
acids. Meyer's primary aim was to ascertain the constitution of
benzene derivatives.
Meyer proposed in 1872 the existence of two series of isometric
organic nitrogen compounds. During his year at Stuttgart, he
discovered a general method for the preparation of nitroparaffins
and investigated this problem during his first four years at
Zurich. He explored this area so thoroughly that, it was
acclaimed at the time of his death, almost all that was known
about nitro compounds was due to Meyer, and his students.
Meyer then explored a variety of organic nitrogen compounds and
discovered several new types. The most important was his
preparation of the first oximes through the reaction between
hydroxylamine and an aldehyde. A new area of investigation that
he stumbled on was by a lecture demonstration that failed. He
wanted to show the students that the addition of isatin and
sulphuric acid to benzene produces the blue colour reaction. The
results were negative.
Meyer took up the investigations of the Baeyer's indophenine test
for benzene. He proposed several hypotheses, one of which was
that coal-tar benzene was a mixture of two substances with
similar properties and that only one of these substances combined
with isatin. In 1883 he isolated this substance and named it
``thiophene'', because of its similarity to phenyl compounds. He
also proved that it had a ring structure.
Victor Meyer got world-wide renown with the vapour density method
he invented. Devised in three stages from 1876, it was a product
of his researches: for he had to determine the molecular formulae
of the substances with which he was working.
There were several methods then available but he evolved a
different technique that utilised small amounts of a substance
and that could be used at high temperatures. The principle of his
method is that the vapour of a weighed substance displaces an
equal volume of air, which in turn is measured by means of a
burette. Meyer's apparatus is now standard equipment in most
chemical laboratories.
Meyer's gifts as a dramatist came to his aid to captivate his
students who were attracted from both Europe and North America.
His concern for excellence in teaching found expression in taking
up a project with his assistant Paul Jacobson. He wrote a two-
volume work ``Treatise on organic chemistry'', which still
remains a classic. Meyer's happy family life, with wife and five
children was marred by frequent illness. His health declined
during the1880's when he suffered from neuralgic pains and
insomnia. He became conscious that his long suffering was
affecting his thought power: suddenly he ended his life (August
8, 1897) by taking prussic acid.
R.Parthasarathy
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