Revolutionary applications in lithography, nanotechnology

THE ACHIEVEMENT of Bose-Einstein condensation in dilute gases of alkali atoms, and for early fundamental studies of the properties of the condensates have earned the Nobel Prize jointly to Eric A. Cornell, Wolfgang Ketterle and Carl E. Wiemann. The Bose-Einstein condensation in dilute gases offers particularly rich possibilities for studies of fundamental quantum-mechanical processes. It will be possible to exploit the BEC phenomenon in gases in precision measurements of fundamental natural phenomena where sharp resonances in essentially motionless atoms or sharp matter-interference fringes are used

New state of matter revealed

The matter surrounding us consists of atoms that obey the laws of quantum mechanics. At normal temperatures these often agree with classical conceptions, and a gas under these conditions behaves rather like a swarm of billiard balls bouncing against one another and the containing walls. When the temperature is lowered and the speed of the atoms is reduced, however, their properties will be increasingly dominated by the principles of quantum mechanics. The atoms rotate round their axes they have spin and this movement is described by a spin quantum number, which has to be an integer a whole number or a half-integer. Particles that have integer spin are called bosons, while those with half- integer spin are called fermions. Bosons show strong "social" behaviour and at low temperatures strive to gather in one and the same quantum state, the one with the lowest energy. Fermions on the other hand avoid one another. They cannot appear in exactly the same quantum state, so that states of higher energy must also be used. The arrangement of elements in the periodic system may be understood on the basis of the fact that electrons in atomic shells are fermions.

As early as 1924 the Indian physicist S. N. Bose carried out a statistical calculation for the kind of particles which have since come to bear his name, bosons, and more specifically light particles later termed photons.

Bose presented an alternative derivation for the radiation law earlier found by Planck. Bose sent his work to A. Einstein, who realised its importance. He translated it to German and had it published. Einstein rapidly extended the theory to cover

Bose particles with mass and he himself published two articles in quick succession, predicting that when a given number of particles approach each other sufficiently closely and move sufficiently slowly they will together convert to the lowest energy state: what we now term Bose-Einstein condensation (BEC) occurs.

Ever since publication of this pioneering work, physicists have wished to be able to achieve this new fundamental state of matter, which was expected to have many interesting and useful properties.

The prize winners using very advanced methods, finally managed to do this in 1995. The state was achieved in alkali atom gases, in which the phenomenon can be studied in a very pure manner.

Nowhere else in the universe can one find the extreme conditions which BEC in dilute gases represents. Manifestations of Bose- Einstein condensation have earlier been observed in more complicated systems: condensation of paired electrons in superconductors (loss of all electrical resistance) and suprafluidity (loss of internal friction in fluids). Here, too, low temperatures are required.

Research in these areas has been rewarded with several Nobel Prizes. As opposed to alkali-atom vapours these quantum- mechanical systems are not simple since the condensation phenomenon concerns only a part of the systems and the strong interactions involved tend to hide the BEC phenomenon.

Waves or particles?

According to the laws of quantum mechanics that govern conditions in the microcosmos, what we normally term a particle can sometimes behave like a wave.

The more slowly the particle moves the less its momentum and the longer the de Broglie wavelength. According to the kinetic theory of gases low particle velocities correspond to low temperatures. If a sufficiently dense gas of cold atoms can be produced, the matter wavelengths of the particles will be of the same order of magnitude as the distance between them.

It is at that point that the different waves of matter can 'sense' one another and co-ordinate their state, and this is Bose-Einstein

It is sometimes said that a "superatom" arises since the whole complex is described by one single wave function exactly as in a single atom. We can also speak of coherent matter in the same way as of coherent light in the case of a laser.

Gases when cooled generally condense into liquids. This must be avoided and, as this year's Nobel Laureates have shown, this is possible with alkali atoms. For rubidium with mass number 87, {+8}{+7}Rb, and sodium with its stable isotope 23Na, which both have integer atomic spin, weak repulsive forces arise between the atoms in each case.

It can be shown that BEC occurs if the density, exceeds 2.6. It can then be calculated that the atoms for realistic densities must move very slowly, at speeds of the order of a few millimetres per second. This corresponds to temperatures of the order of 100 nK (nanokelvin), i.e. a tenth of a millionth of a degree above absolute zero.

This year's Nobel Laureates achieved this by using in a decisive manner the methods of cooling and trapping neutral atoms for which the Nobel Prize in Physics was awarded in 1997 (S. Chu, C. Cohen-Tannoudji and W. D. Phillips).

Laser cooling and evaporative cooling lead to BEC

The basic principle is to exchange momentum between photons and atoms. Cooling is achieved by arranging that the photons can be absorbed only if they collide head-on with the atom in its flight.

The speed is then reduced, primarily to a limit set by the randomness course of spontaneous emission. The 1997 Nobel Laureates showed that what is termed the Doppler limit can be overcome using refined processes, so that considerably lower temperatures can be achieved.

However the cloud of cooled atoms must also be held together, and this can take place in what are termed atom traps. These often work on a combination of laser beams and magnetic fields.

The magneto-optical trap (MOT) has become specially important. Several research groups have used this technique for approaching BEC conditions. However a further cooling technique proved necessary, evaporative cooling, which was employed in D. Kleppner's and T. J. Greytak's group at MIT. Here the medium is cooled by ensuring that the fastest atoms leave the community. The average temperature among those remaining then is reduced.

The coffee in a cup cools in a similar fashion! In an atom trap the atoms are kept in place by magnetic dipole forces. The attractive force can be turned into a repelling force if the atomic magnetic poles are reversed.

This can be achieved with a radio-frequency field, an effective method proposed by D. E. Pritchard at MIT. The most rapid atoms move high up at the edge of the potential well, where the magnetic field and hence conversion frequency for pole switching is high.

By initially applying a high frequency and then gradually lowering it, it is possible to successively skim off the hot atoms. In this way the group led by Cornell and Wieman, managed, in June 1995, for the first time, to achieve a condensation limit in {+8}{+7}Rb. A final difficulty to overcome was to avoid atom loss at the centre of the trap, where the magnetic field is zero and spontaneous pole-switching is possible.

By rotating a magnetic field sufficiently rapidly over the sample, it was possible to prevent the atoms from systematically pouring out of the trap.

Around 1990 Wieman drew up guidelines for how BEC could be achieved in alkali atoms. Important aspects were laser cooling in a MOT and transfer to a purely magnetic trap in which evaporative cooling could then be applied. Cornell was hired by Wieman to work on the project, initially as a "postdoc", but was soon permanently employed at NIST.

In the JILA experiments the process was initiated at a temperature of approximately 170 nK. By making the evaporative cooling more effective a pure condensate was obtained with a temperature of 20 nK. About 2 000 atoms then remained in the sample.

Ketterle worked using sodium atoms which absorb and emit yellow light. Ketterle solved the problem of atom losses at the centre of the trap by focusing there a powerful laser beam which kept the atoms away from the loss area.

Prospects

Bose-Einstein condensation in dilute gases offers particularly rich possibilities for studies of fundamental quantum-mechanical processes. The influence on other research areas is also great. Recently the JILA group has demonstrated that with {+8}{+5}Rb it is possible using the above-mentioned resonances to switch rapidly between attractive and repulsive atomic forces, leading to dissolution of the condensate that resembles that of a supernova (the "Bose-nova").

Studies of phenomena related to BEC for fermions at extremely low temperatures by D. Jin and co-workers at JILA are revealing new aspects of the statistical conditions in physical systems, indicating future possibilities of observing atomic pair- formation and suprafluidity properties. R. G. Hulet's group has shown that an outward pressure arises because of the repulsive nature of fermions in a degenerate atomic Fermi gas, and that conditions resembling those in white dwarf stars can be simulated.

It will be possible to exploit the BEC phenomenon in gases in precision measurements of fundamental natural phenomena where sharp resonances in essentially motionless atoms or sharp matter- interference fringes are used. Revolutionary applications of BEC in lithography, nanotechnology and holography appear to be just round the corner.

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